考虑转供容量约束的配电网马尔可夫可靠性算法

将马尔可夫理论应用于配电网的可靠性评估中,将一台虚拟的故障主变和一条虚拟的故障线路作为负荷失电时候的状态,视为当供电线路故障,并且转供不成功的情况下,状态转移至由这条虚拟的故障线路供电.利用主变和线路间的联络关系,充分考虑了系统发生N-1故障时的转供成功率,并且综合了系统的元件故障率,形成马尔可夫转移概率矩阵.采用经典的马尔可夫状态空间法,准确全面且简便地求解配电网的可靠率,并通过一个实际的配电网络算例验证了算法的可用性.     

改进的人工免疫分类算法在故障类型识别中的应用

提出将小波包变换和改进的免疫算法相结合,对输电线路故障类型进行识别.运用小波包将电压故障信号分解,提取三相的小波奇异熵作为免疫网络的抗原,利用免疫网络抗原一抗体识别原理进行故障类型识别.仿真结果表明:在相同实验条件下,与传统的ANN网络和SVM相比,该算法具有自适应连续学习的功能,对故障诊断系统可以连续不断的补充新样本.并且此故障类型识别方法不受系统运行方式、过渡电阻和故障位置等影响,具有较强的通用性,较高的精度,识别速度快和算法简单易实现.     

Particle motion and separation in a laminar tube flow with downstream enlargement

Particle classification becomes difficult when the difference in density between particle and fluid is low or negligible and the fluid is viscous. For such applications, a process capable of separating the particles according to their size is needed. Such applications are, e.g. found in biological systems for cell separation or in the removal of gel particles from polymer melts. Particle transport in laminar tube flows at low but non zero Reynolds numbers leads to accumulation of large particles near the tube center and forms a particle free zone near the wall. Small particles find their position on their equilibrium radius. Downstream widening of the flow enhances segregation between large and small particles. Large particles can be collected in a centered collector tube downstream, whereas small particles follow their streamlines around the collector tube and can be removed with the remaining flow. The said particle migration is observed when the ratio of particle to tube diameter is 0.2<d/D<0.51 and the tube Reynolds number is in between 0.2<Re<40. CFD simulations reveal the shape of the streamlines in the downstream enlargement with different tube Reynolds number. The efficiency of the classification process is characterized. Particles need a sufficient transportation length in the tube for proper demixing. This effect is analyzed by a laser sheet illuminated system within an acrylic glass tube.     

Influence of 4-N,N-dimethylaminopyridine on the photovoltaic performance of dye-sensitized solar cells with poly(ethyleneoxide)/oligo(ethylene glycol) blend electrolytes

4-N,N-Dimethylaminopyridine (DMAP) was introduced into poly(ethyleneoxide)/oligo(ethylene glycol) (PEO/PEG) electrolytes for dye-sensitized solar cells (DSCs). The improved photovoltaic performance of DMAP-doped DSCs was attributed to the integrated effects of the upward displacement of the TiO₂ band edge and the decrease in the electron recombination rate. Remarkably, the presence of DMAP suppresses electron recombination via two combined pathways involving the dissociation of triiodide to iodide by a complexation reaction and a modification of the surface state distribution in the band gap of TiO₂. With the addition of DMAP, the open-circuit voltage enhances dramatically. The short-circuit photocurrent density has a small increase at low DMAP concentration and drops afterwards. The power conversion efficiency is 4.07%, which corresponds to a 63% increase over that of the DSC without DMAP.     

Synthesis of LiFe0.4Mn0.6?xNixPO4/C by co-precipitation method and its electrochemical performances

LiFe_0.4Mn_0.6−x Ni _x PO₄/C(x = 0, 0.05, 0.1, and 0.2) composite cathode materials for lithium ion batteries have been prepared by the co-precipitation method using oxalic acid as a precipitator. The structure and morphology of precursors and products have been investigated. Electrochemical tests demonstrate that LiFe_0.4Mn_0.55Ni_0.05PO₄ can deliver a specific capacity of 142 mAh g⁻¹ at 0.1 C, and retains 133 mAh g⁻¹ after 60 cycles. The rate performance of LiFe_0.4Mn_0.6PO₄ is obviously improved by doping Ni. The capacity of LiFe_0.4Mn_0.55Ni_0.05PO₄ at 2 C is 110 mAh g⁻¹.     

组合填料曝气生物滤池处理受污地表水的研究

采用陶粒-沸石-活性炭组合填料曝气生物滤池,对受污地表水体的处理效能进行了研究,考察了气水比和水力负荷对曝气生物滤池处理效果的影响.结果表明,气水比、水力负荷对COD的去除效果影响较大,而对氨氮含量和浊度的去除效果影响很小;在气水体积比为2:1、水力负荷为0.382 m3· m-2·h-1、温度为16～31℃的条件下,组合填料曝气生物滤池具有较好处理效果,出水CODMn和氨氮的质量浓度分别在2 mg·L-1和0.15 mg·L-1以下.     

Synthesis and application of long‐chain alkyl quaternary ammonium‐functionalized hyperbranched polyester

A novel kind of macromolecule, long‐chain alkyl quaternary ammonium functionalized hyperbranched polyester (QHPE), was synthesized by the reaction of hyperbranched polyester Boltorn H30 (H30) and 2,3‐epoxypropyl alkyl dimethyl ammonium chloride under alkaline conditions in dimethylformamide. After modification, the hydroxyl terminal group of H30 was converted into an ammonium functional group. A series of products was obtained with different lengths of an alkyl chain (C8, C12, C16, and C18) in the ammonium functional group. All of the products were characterized by Fourier transform infrared and NMR spectroscopy. The application of QHPEs as accelerators for the alkaline hydrolysis of poly(ethylene terephthalate) (PET) fabric was studied. The influences of the structure of QHPEs and hydrolysis conditions, such as alkaline concentration, hydrolysis time, and temperature, on the weight loss of PET fabrics were investigated. The results indicated that QHPE was a novel, efficient accelerator for the alkaline hydrolysis of PET fabrics. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Nonisothermal crystallization behavior of highly exfoliated polypropylene/clay nanocomposites prepared by in situ polymerization

Polypropylene/clay nanocomposites (PPCNs) were prepared via an in situ polymerization method with a Ziegler–Natta/clay compound catalyst in which the MgCl₂/TiCl₄ catalyst was embedded in the clay galleries. The wide‐angle X‐ray diffraction and transmission electron microscopy results showed that the clay particles were highly exfoliated in the polypropylene (PP) matrix. The nonisothermal crystallization kinetics of these PPCNs were investigated by differential scanning calorimetry at various cooling rates. The nucleation activity were calculated by Dobreva's method to demonstrate that the highly dispersed silicate layers acted as effective nucleating agents. The Avrami, Jeziorny, Ozawa, and Mo methods were used to describe the nonisothermal crystallization behavior of the PP and PPCNs. Various parameters of nonisothermal crystallization, such as the crystallization half‐time, crystallization rate constant, and the kinetic parameter F(t), reflected that the highly exfoliated silicate layers significantly accelerated the crystallization process because of its outstanding nucleation effect. The activation energy values of the PP and PPCNs determined by the Kissinger method increased with the addition of the nanosilicate layers. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Synthesis and characterization of alkali‐soluble photosensitive polysiloxane urethane acrylate

A new negative temperature coefficient of resistor (NTCR) thermistors based on nitrile butadiene rubber/magnetite (NBR/Fe₃O₄) nanocomposites were successfully fabricated by conventional roll milling technique. X‐ray diffraction and transmission (TEM) analysis showed that the product is mainly magnetite nanoparticles with diameter of 10‐13 nm. The microstructure of (NBR/Fe₃O₄) nanocomposites were examined by scanning electron microscopy (SEM) and FTIR spectroscopy. The dispersion of magnetite nanoparticles in the NBR rubber matrix and interfacial bonding between them were rather good. The thermal stability of nanocomposites was also obviously improved with the inclusion of the magnetite nanoparticles. The thermal conductivity, thermal diffusivity and specific heat of nanocomposites were investigated. The electrical conductivity of the NBR/Fe₃O₄ increases with the rise in temperature exhibiting a typical negative temperature coefficient of resistance (NTCR) behavior like a semiconductor. The nature of the temperature variation of electrical conductivity and values of activation and hopping energy, suggest that the transport conduction process is controlled by hopping mechanism. Values of characteristics parameters of the thermistors like thermistor constant, thermistor sensitivity and thermistor stability is quite good for practical application as NTCR devices at high temperature. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Colloidal properties of copolymer‐encapsulated and surface‐modified pigment dispersion and its application in inkjet printing inks

A styrene–maleic acid copolymer (PSMA)‐encapsulated 2‐[(2‐methoxy‐4‐nitrophenyl) azo]‐N‐(2‐methoxyphenyl)‐3‐oxobutyramide (PY74) dispersion was prepared by the phase‐separation technique. A surface‐modified PY74 dispersion was prepared with PSMA sodium as a dispersant by the milling method. Furthermore, the two dispersions were applied to formulate pigment inks. The colloidal properties of these two dispersions were compared. The printing and color performance of the prepared inks were also investigated. The results show that the PSMA‐encapsulated PY74 dispersion with a small particle size had higher stabilities of NaCl concentration, pH value, and temperature than the surface‐modified PY74 dispersion. The apparent viscosity of the PSMA‐encapsulated PY74 dispersion changed little, while it changed greatly in the surface‐modified PY74 dispersion with an increase of the shear rate from 10 to 100 s⁻¹. The ink printing and color performance of printed Fabrics indicated that the PSMA‐encapsulated PY74 dispersion was more suitable for the preparation of inkjet printing ink than the surface‐modified PY74 dispersion. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011